Synthesis of triazolium-based mono- and tris-branched [1]rotaxanes using a molecular transporter of dibenzo-24-crown-8† †Electronic supplementary information (ESI) available: Full experimental procedures and characterization data for all compounds. See DOI: 10.1039/c5sc01722j Click here for additional data file.

Synthesis of triazolium-based mono- and tris-branched [1]rotaxanes using a molecular transporter of dibenzo-24-crown-8.

We report a diverted route to [1]rotaxane and tris-branched [1]rotaxane that are devoid of any efficient template and which could not be obtained by classical straightforward strategies. The described chemical route relies on the utilization of a "macrocycle transporter", which is able first to bind a macrocycle, second to link temporarily a triazolium-containing molecular axle, and third to de...

Synthesis and stabilities of peptide-based [1]rotaxanes: molecular grafting onto lasso peptide scaffolds† †Electronic supplementary information (ESI) available: Experimental procedures and analytical data of all new compounds. CCDC 1520783. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc00021a Click here for additional data file. Click here for additional data file.

Unified synthesis of mono/bis-arylated phenols via RhIII-catalyzed dehydrogenative coupling† †Electronic supplementary information (ESI) available: Experimental procedures and characterization data for all new compounds. CCDC 1047606, 1426755, 1438599 and 1442845. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc03169b Click here for additional data file. Click here for additional data file.

Impact of mechanical bonding on the redox-switching of tetrathiafulvalene in crown ether–ammonium [2]rotaxanes† †Electronic supplementary information (ESI) available: Synthetic procedures and full characterisation of new compounds, tandem MS experiments, ITC data, full electrochemical experiments and additional NMR data. See DOI: 10.1039/c7sc02694c Click here for additional data file.

Facile synthesis of oligoyne amphiphiles and their rotaxanes† †Electronic supplementary information (ESI) available: Fig. S1–S4 and a comprehensive account of all experimental details, including synthetic procedures, analytical data, and NMR spectra of all novel compounds. See DOI: 10.1039/c4sc03154g Click here for additional data file.